Title of article :
An enyne metathesis/Diels–Alder reaction sequence towards the synthesis of cup-shaped 5/5/6-tricyclic architectures
Author/Authors :
Jego-Evanno، نويسنده , , Laurent and Deville، نويسنده , , Alexandre and Bodo، نويسنده , , Bernard and Nay، نويسنده , , Bastien، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
A strategy to synthesize the 5/5/6-tricyclic framework of presilphiperfolane natural products is described, involving a model dienyne compound (I). The key steps are an enyne metathesis reaction to introduce the diene part and a Diels–Alder cycloaddition to reveal the tricyclic architecture.
Keywords :
Enyne metathesis , Diels–Alder cycloaddition , Fused tricyclic structure , Catalysis , carbonylation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
