Title of article
A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins
Author/Authors
Yang، نويسنده , , Cheng and Nishijima، نويسنده , , Masaki and Nakamura، نويسنده , , Asao and Mori، نويسنده , , Tadashi and Wada، نويسنده , , Takehiko and Inoue، نويسنده , , Yoshihisa، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
4357
To page
4360
Abstract
The enantiodifferentiating [4+4] photocyclodimerization of anthracenecarboxylic acid (AC) mediated by native, mono- and di-3,6-anhydro-γ-cyclodextrins was investigated in both aqueous solution and solid-state. The solid-state photolyses gave inherently disfavored head-to-head photodimers in much higher chemical and optical yields than in the aqueous solution.
Keywords
Photocyclodimerization , 6-Anhydro-?-cyclodextrin , SOLID-STATE , Anthracenecarboxylic acid , 3
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1855256
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