Title of article
The relative reactivities of various unsaturated compounds towards diisopropyloxy(η2-cyclopentene)titanium
Author/Authors
Cadoret، نويسنده , , Frédéric and Six، نويسنده , , Yvan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
5491
To page
5495
Abstract
Competition experiments were performed by adding pre-formed solutions of diisopropyloxy(η2-cyclopentene)titanium in diethyl ether to various mixtures of unsaturated compounds at low temperature, establishing the following reactivity scale: aldehyde > nitrile > ketone > terminal alkyne > internal alkyne > terminal alkene > ester, carbonate.
Keywords
Kulinkovich reaction , ligand exchange , Pinacol coupling , Titanium , titanacyclopropanes
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1855848
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