Title of article :
The relative reactivities of various unsaturated compounds towards diisopropyloxy(η2-cyclopentene)titanium
Author/Authors :
Cadoret، نويسنده , , Frédéric and Six، نويسنده , , Yvan، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
Competition experiments were performed by adding pre-formed solutions of diisopropyloxy(η2-cyclopentene)titanium in diethyl ether to various mixtures of unsaturated compounds at low temperature, establishing the following reactivity scale: aldehyde > nitrile > ketone > terminal alkyne > internal alkyne > terminal alkene > ester, carbonate.
Keywords :
Kulinkovich reaction , ligand exchange , Pinacol coupling , Titanium , titanacyclopropanes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
