Title of article
Efficient one-pot trans-dihydroxylation of 2H-pyrans using dimethyldioxirane (DMD): synthesis of trans-3,4-dihydroxy-3,4-dihydro-O-methyloctandreolones, orixalone D, and trans-3,4-dihydroxy-3,4-dihydromollugin natural products
Author/Authors
Wang، نويسنده , , Xue and Lee، نويسنده , , Yong Rok، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
6
From page
6275
To page
6280
Abstract
An efficient one-pot formation of trans-diols on 2H-pyranyl rings was achieved by dimethyldioxirane in wet acetone. This new methodology was applied to the synthesis of natural products containing trans-diol on the pyranyl rings such as trans-3,4-dihydroxy-3,4-dihydro-O-methyloctandreolones, orixalone D, and trans-3,4-dihydroxy-3,4-dihydromollugin.
Keywords
Trans-3 , 4-Dihydroxy-3 , Trans-3 , 4-dihydro-O-methyloctandreolones , 4-Dihydroxy-3 , Orixalone D , 4-dihydromollugin , Dimethyldioxirane , trans-Dihydroxylation
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856281
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