Title of article
Photo-labeling of C60 with 3-trifluoromethyl-3-phenyldiazirine
Author/Authors
Sato، نويسنده , , Satoru and Yamada، نويسنده , , Michio and Wakahara، نويسنده , , Takatsugu and Tsuchiya، نويسنده , , Takahiro and Ishitsuka، نويسنده , , Midori O. and Akasaka، نويسنده , , Takeshi and Liu، نويسنده , , Michael T.H.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
6290
To page
6293
Abstract
The photochemical reaction of C60 with 3-trifluoromethyl-3-phenyldiazirine affords a photo-labeled C60 derivative. The derivative was characterized by mass, UV–vis absorption, NMR spectroscopy, and X-ray crystallographic analysis. The redox potentials of this derivative were also investigated by means of CV and DPV. This photo-labeling method to the fullerene surface is expected to be effective for constructing various kinds of bio-functionalized fullerenes.
Keywords
C60 , 3-Trifluoromethyl-3-phenyldiazirine , Carbene , Photoaffinity labeling
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856287
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