Author/Authors :
Sato، نويسنده , , Satoru and Yamada، نويسنده , , Michio and Wakahara، نويسنده , , Takatsugu and Tsuchiya، نويسنده , , Takahiro and Ishitsuka، نويسنده , , Midori O. and Akasaka، نويسنده , , Takeshi and Liu، نويسنده , , Michael T.H.، نويسنده ,
Abstract :
The photochemical reaction of C60 with 3-trifluoromethyl-3-phenyldiazirine affords a photo-labeled C60 derivative. The derivative was characterized by mass, UV–vis absorption, NMR spectroscopy, and X-ray crystallographic analysis. The redox potentials of this derivative were also investigated by means of CV and DPV. This photo-labeling method to the fullerene surface is expected to be effective for constructing various kinds of bio-functionalized fullerenes.
Keywords :
C60 , 3-Trifluoromethyl-3-phenyldiazirine , Carbene , Photoaffinity labeling
