Title of article
Intramolecular 1,5-hydrogen atom transfer reaction promoted by phosphoramidyl and carbamoyl radicals: synthesis of 2-amino-C-glycosides
Author/Authors
Francisco، نويسنده , , Cosme G. and Herrera، نويسنده , , Antonio J. and Martيn، نويسنده , , ءngeles and Pérez-Martيn، نويسنده , , Inés and Suلrez، نويسنده , , Ernesto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
6384
To page
6388
Abstract
The preparation of 2-amino-C-glycosides of the hexahydro-2H-furo[3,2-b]pyrrole and octahydropyrano[3,2-b]pyrrole systems is described. A tandem 1,5-hydrogen atom transfer–radical oxidation–nucleophilic cyclisation mechanism is proposed for the intramolecular hydrogen atom transfer reaction promoted by carbamoyl and phosphoramidyl radicals employing hipervalent iodine oxidants.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856350
Link To Document