Title of article
Synthetic studies on (−)-FR182877: construction of the ABCD ring system via the intramolecular cycloadditions (2)
Author/Authors
Tanaka، نويسنده , , Natsumi and Suzuki، نويسنده , , Takahiro and Hosoya، نويسنده , , Yosuke and Nakada، نويسنده , , Masahisa، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
6488
To page
6492
Abstract
Construction of the ABCD ring system of (−)-FR182877 via the intramolecular Diels–Alder (IMDA) reaction and the highly diastereoselective intramolecular hetero-Diels–Alder (IMHDA) reaction is described. The IMHDA reactions of the substrates incorporating the oxabutadiene with the E- or Z-alkene were examined, revealing that the sole product was obtained from both substrates and the E-alkene geometry was found to be crucial to obtaining the desired product.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856399
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