Title of article :
Katsuki–Jacobsen oxidation–epoxidation of α-silyloxy sulfinyl dienes: application to the formal synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol
Author/Authors :
de la Pradilla، نويسنده , , Roberto Fernلndez and Castellanos، نويسنده , , Alejandro، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
The Katsuki–Jacobsen oxidation–epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans sulfonyl dihydrofurans with good selectivities. As an application, the formal synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol is reported.
Keywords :
Katsuki–Jacobsen epoxidation , tetrahydrofurans , sulfoxides
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
