Author/Authors :
Nagata، نويسنده , , Shoko and Kawaguchi، نويسنده , , Shin-ichi and Matsumoto، نويسنده , , Michiko and Kamiya، نويسنده , , Ikuyo and Nomoto، نويسنده , , Akihiro and Sonoda، نويسنده , , Motohiro and Ogawa، نويسنده , , Akiya، نويسنده ,
Abstract :
A novel palladium-catalyzed hydrophosphination of alkynes with tetraphenyldiphosphine takes place regioselectively to provide vinylic phosphines, which undergo air-oxidation during workups, affording the corresponding vinylphosphine oxides in good yields.