Author/Authors :
Gonda، نويسنده , , Jozef and Martinkov?، نويسنده , , Miroslava and Zadro?ov?، نويسنده , , Andrea and ?otekov?، نويسنده , , Monika and Raschmanov?، نويسنده , , Jana and ?onka، نويسنده , , Patrik and Gajdo??kov?، نويسنده , , Eva and Kappe، نويسنده , , C. Oliver، نويسنده ,
Abstract :
The microwave-assisted thermal aza-Claisen rearrangement of allylic imidates and thiocyanates to the corresponding amides and isothiocyanates is investigated. Significant accelerations of the rearrangement of allylic imidates to amides and of allylic thiocyanates to isothiocyanates in comparison with standard thermal reactions is observed.
Keywords :
Overman rearrangement , Imidate , Thiocyanate , Isothiocyanate , microwave irradiation