Title of article :
A stereoselective total synthesis of (−)-andrachcinidine via an olefin cross-metathesis protocol
Author/Authors :
Radha Krishna، نويسنده , , Palakodety and Dayaker، نويسنده , , G.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
A stereoselective total synthesis of 1-(2S,6R)-6-[(2S)-2-hydroxypentyl]-hexahydro-2-pyridinylacetone, (−)-andrachcinidine is reported. The strategy utilizes olefin cross-metathesis and intramolecular SN2 cyclization as the key steps.
Keywords :
Garner’s aldehyde , 1 , Sharpless asymmetric epoxidation , Grubbs’ catalyst , olefin cross-metathesis , Intramolecular SN2 cyclization , Hydroboration , 3-anti Chiral allylation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
