Title of article
Diastereoselective reductive Mannich-type coupling of acrylates and aldimines with Rh(Phebox) catalyst
Author/Authors
Nishiyama، نويسنده , , Hisao and Ishikawa، نويسنده , , Junji and Shiomi، نويسنده , , Takushi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
7841
To page
7844
Abstract
The conjugate reduction of α,β-unsaturated esters such as acrylates, crotonate, and cinnamates followed by Mannich-type coupling toward aldimines was efficiently promoted by rhodium-bis(oxazolinyl)phenyl catalyst and alkoxyhydrosilanes to show high anti-selectivity up to 99.
Keywords
Mannich reaction , Rhodium , Bisoxazoline , Conjugate reduction
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857092
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