Title of article :
Direct addition of supercritical alcohols, acetone or acetonitrile to the alkenes without catalysts
Author/Authors :
Kamitanaka، نويسنده , , Takashi and Hikida، نويسنده , , Tatsuyoshi and Hayashi، نويسنده , , Satoshi and Kishida، نويسنده , , Nobuhiro and Matsuda، نويسنده , , Tomoko and Harada، نويسنده , , Tadao، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
The reactions of the alkenes with supercritical organic compounds under non-catalytic conditions were investigated. The H and CR2OH, CH2COCH3 or CH2CN of supercritical alcohols (CHR2OH), acetone (CH3COCH3) or acetonitrile (CH3CN) added to the CC bonds of alkenes form C–C bonds between the α-carbons of the supercritical organic compounds and the sp2 carbons of the alkenes.
Keywords :
Carbon–carbon bond forming reaction , Acetonylation , Hydroxyalkylation , Uncatalyzed reaction , Supercritical fluid
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
