مرکز منطقه ای اطلاع رساني علوم و فناوري - Enantiodifferentiating tetrahydrofuranylation of but-3-enyl carboxylates using optically active hypervalent iodine(III) reagents via a 1,3-dioxan-2-yl cation intermediate

Title of article :

Enantiodifferentiating tetrahydrofuranylation of but-3-enyl carboxylates using optically active hypervalent iodine(III) reagents via a 1,3-dioxan-2-yl cation intermediate

Author/Authors :

Fujita، نويسنده , , Morifumi and Okuno، نويسنده , , Sakuro and Lee، نويسنده , , Hee Jin and Sugimura، نويسنده , , Takashi and Okuyama، نويسنده , , Tadashi، نويسنده ,

Issue Information :

هفته نامه با شماره پیاپی سال 2007

Pages :

From page :

8691

To page :

8694

Abstract :

Optically active methyl 2-[2-(diacetoxyiodo)phenoxy]propanoate and its derivative were prepared and used for oxygenation of but-3-enyl carboxylates leading to tetrahydrofuran-3-yl carboxylates as an enantiomerically enriched form.

Keywords :

Neighboring group participation , Iodosylbenzene , asymmetric synthesis , hypervalent iodine

Journal title :

Tetrahedron Letters

Serial Year :

2007

Journal title :

Tetrahedron Letters

Record number :

1857464

Link To Document :

https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1857464