Title of article
Enantiodifferentiating tetrahydrofuranylation of but-3-enyl carboxylates using optically active hypervalent iodine(III) reagents via a 1,3-dioxan-2-yl cation intermediate
Author/Authors
Fujita، نويسنده , , Morifumi and Okuno، نويسنده , , Sakuro and Lee، نويسنده , , Hee Jin and Sugimura، نويسنده , , Takashi and Okuyama، نويسنده , , Tadashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
8691
To page
8694
Abstract
Optically active methyl 2-[2-(diacetoxyiodo)phenoxy]propanoate and its derivative were prepared and used for oxygenation of but-3-enyl carboxylates leading to tetrahydrofuran-3-yl carboxylates as an enantiomerically enriched form.
Keywords
Neighboring group participation , Iodosylbenzene , asymmetric synthesis , hypervalent iodine
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857464
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