Author/Authors :
Bonnafoux، نويسنده , , Laurence and Scopelliti، نويسنده , , Rosario and Leroux، نويسنده , , Frédéric R. and Colobert، نويسنده , , Françoise، نويسنده ,
Abstract :
A solvent-dependent silyl migration of lithiated biphenyls is described, involving the intermediate formation of a pentacoordinated silicate complex. Differences in the relative basicities of the aryllithium intermediates are the possible driving force for this migration.
