Title of article
Zincate-type enolate for radical α-trifluoromethylation
Author/Authors
Tomita، نويسنده , , Yuichi and Ichikawa، نويسنده , , Yoshiyuki and Itoh، نويسنده , , Yoshimitsu and Kawada، نويسنده , , Kosuke and Mikami، نويسنده , , Koichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
8922
To page
8925
Abstract
Ketone zincate-type enolates can be applied to radical trifluoromethylation for the general synthesis of α-CF3-ketones, cyclopentanones in particular. The addition of diethylzinc to lithium enolates is the key in the preparation of the zincate-type enolates for efficient radical trifluoromethylation.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857551
Link To Document