Title of article
First synthesis of 4a-carba-β-d-galactofuranose
Author/Authors
Jens Frigell، نويسنده , , Jens and Cumpstey، نويسنده , , Ian، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
9073
To page
9076
Abstract
The synthesis of 4a-carba-β-d-galactofuranose is described starting from diacetone glucose. The key ring-closure step was carried out by metathesis to form a cyclopentene. Catalytic hydrogenation of the CC double bond gave the galacto configured saturated carbahexofuranose with excellent diastereoselectivity.
Keywords
Carbasugars , galactofuranose , glycomimetics , ring-closing metathesis
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857587
Link To Document