Title of article :
Reduction of sulfoxides with boranes catalyzed by MoO2Cl2
Author/Authors :
Fernandes، نويسنده , , Ana C. and Romمo، نويسنده , , Carlos C.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2007
Abstract :
The first example of an organic reduction with boranes catalyzed by a high valent oxo-complex is reported. The systems catecholborane/MoO2Cl2(H2O)2 (5 mol %) and BH3·THF/MoO2Cl2 (5 mol %) proved to be very efficient for the reduction of sulfoxides to the corresponding sulfides in excellent yields.
Keywords :
Reduction , sulfoxides , Dioxomolybdenum dichloride , B–H Activation , Boranes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
