Title of article
Stereoselective synthesis of chiral tertiary alcohol building blocks via neighbouring group participation from tri-substituted olefins
Author/Authors
Raghavan، نويسنده , , Sadagopan and Sreekanth، نويسنده , , T.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
6
From page
1169
To page
1174
Abstract
A regio- and stereoselective preparation of chiral quaternary 1,2/1,3-diols from acyclic tri-substituted alkenes is disclosed. Optically active tertiary alcohols are the constituents of several bioactive natural products, pharmaceuticals and a general method for their preparation is desirable. A sulfinyl moiety has been utilized as an intramolecular nucleophile.
Keywords
3-Diols , Sulfoxide , Tri-substituted alkenes , 2/1 , Chiral quaternary 1
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858211
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