Author/Authors :
Averin، نويسنده , , Alexei D. and Ranyuk، نويسنده , , Elena R. and Lukashev، نويسنده , , Nikolai V. and Golub، نويسنده , , Svetlana L. and Buryak، نويسنده , , Alexei K. and Beletskaya، نويسنده , , Irina P.، نويسنده ,
Abstract :
3,24-Bis(6-chloropyridin-2-yloxy)cholane, obtained from 3,24-cholandiol via a Mitsunobu reaction, was successfully used for the synthesis of a variety of polyazamacrocycles using Pd-catalyzed amination reaction with linear polyamines. The competing formation of cyclodimers and other cyclic oligomers was found to be strongly dependent on the nature of the polyamines employed.
