Author/Authors :
Marciniec، نويسنده , , Bogdan and Pawluc، نويسنده , , Piotr and Hreczycho، نويسنده , , Grzegorz and Macina، نويسنده , , Anna and Madalska، نويسنده , , Martyna، نويسنده ,
Abstract :
A new ruthenium complex-catalyzed O-silylation of silanols with vinylsilanes leading to siloxane bond formation with the evolution of ethylene is described. A maximum conversion of silanol is reached using an excess of vinylsilane to also yield the product of the homo-coupling of the latter. Under the optimum conditions, when vinylsilane with at least one ethoxy substituent is used, the reaction gives exclusively unsymmetrical siloxanes.
