Title of article
A mild and efficient CAN mediated oxidation of Morita–Baylis–Hillman adducts of 5-methyl-N-alkylisatin to 5-formyl-N-alkylisatin
Author/Authors
Shanmugam، نويسنده , , Ponnusamy and Vaithiyanathan، نويسنده , , Vadivel and Selvakumar، نويسنده , , Kodirajan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
2119
To page
2123
Abstract
A simple, mild and efficient CAN mediated oxidation of Morita–Baylis–Hillman adducts of 5-methyl-N-alkylisatins 1a–13a to 5-formyl-N-alkylisatins 1b–13b under ambient reaction conditions is reported. Simple and isomerized 5-methyl-N-alkylisatin derivatives 1–4 have also been tested and failed to provide the corresponding formylated products. A plausible reaction mechanism has been proposed.
Keywords
CAN , Isatin , Aromatic aldehydes , Aryl methyl oxidation , Morita–Baylis–Hillman adduct
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858701
Link To Document