Title of article
Binary 1,4-asymmetric induction from a single allyltin reagent with a chiral nitrogen functional group toward aldehydes
Author/Authors
Nishigaichi، نويسنده , , Yutaka and Tamura، نويسنده , , Kenichi and Ueda، نويسنده , , Narifumi and Iwamoto، نويسنده , , Hidetoshi and Takuwa، نويسنده , , Akio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
4
From page
2124
To page
2127
Abstract
Using a single allyltin reagent with a chiral nitrogen functionality, binary and remote asymmetric induction was realized toward various aldehydes. Either syn- or anti-1,4-amino-alcohols were selectively obtained with the use of Yb(OTf)3 or SnCl4, respectively. The structures of both diastereomers were identified by means of X-ray analysis.
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1858703
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