Title of article :
Generation of rhodium enolates via retro-aldol reaction and its application to regioselective aldol reaction
Author/Authors :
Murakami، نويسنده , , Kei and Ohmiya، نويسنده , , Hirohisa and Yorimitsu، نويسنده , , Hideki and Oshima، نويسنده , , Koichiro، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
Retro-aldol reactions of β-hydroxy ketones take place under rhodium catalysis, leading to regioselective formation of the corresponding rhodium enolates. The enolates react with aldehydes in situ to afford the corresponding aldol adducts in high yields.
Keywords :
aldol reaction , Rhodium , carbon–carbon bond cleavage , Retro-aldol reaction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
