Author/Authors :
Kawatsura، نويسنده , , Motoi and Hirakawa، نويسنده , , Takuya and Tanaka، نويسنده , , Tomoko and Ikeda، نويسنده , , Daiji and Hayase، نويسنده , , Shuichi and Itoh، نويسنده , , Toshiyuki، نويسنده ,
Abstract :
The palladium-catalyzed regioselective allylic amination of α-trifluoromethylated allyl acetate occurred using Pd(OAc)2/DPPE and [Pd(π-allyl)(cod)]BF4/DPPF. The selective formation of the γ-product was attained by Pd(OAc)2/DPPE, while the α-product was obtained using [Pd(π-allyl)(cod)]BF4/DPPF.
Keywords :
Allylic amination , PALLADIUM , fluorine , regioselectivity
