Author/Authors :
Kapuriya، نويسنده , , Naval and Kapuriya، نويسنده , , Kalpana and Dodia، نويسنده , , Narsinh M. and Lin، نويسنده , , Yi-Wen and Kakadiya، نويسنده , , Rajesh and Wu، نويسنده , , Chao-Ting and Chen، نويسنده , , Ching-Huang and Naliapara، نويسنده , , Yogesh and Su، نويسنده , , Tsann-Long، نويسنده ,
Abstract :
Novel rearrangement was found by reacting anilines with HCHO/H2O2 resulting in the synthesis of various benzaldoximes. The mechanism of the rearrangement is proposed and suggested that the rearrangement might proceed via unstable N-phenyloxazirane intermediate followed by the transfer of aryl moiety from nitrogen to carbon atom leading to the formation of benzaldoxime.
Keywords :
Rearrangement , Amines , Peroxides , Benzaldoximes , Oxidation
