Title of article :
Solvent-free synthesis of 1-(p-toluenesulfonyloxy)-1,2-benziodoxol-3(1H)-one from Dess–Martin periodinane and its synthetic utility for α-tosyloxylation of ketones
Author/Authors :
Karade، نويسنده , , Nandkishor N. and Tiwari، نويسنده , , Girdharilal B. and Shinde، نويسنده , , Sandeep V. and Gampawar، نويسنده , , Sumeet V. and Kondre، نويسنده , , Jeevan M.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
The solvent-free synthesis of 1-(p-toluenesulfonyloxy)-1,2-benziodoxol-3(1H)-one is reported from Dess–Martin periodinane and p-toluenesulfonic acid monohydrate using a grinding technique and is subsequently utilized for the α-tosyloxylation of a range of enolisable ketones.
Keywords :
?-Tosyloxylation , PTSA , Solvent-free reactions , Dess–Martin periodinane , hypervalent iodine
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
