Title of article
Nucleophilic substitution at an sp2 carbon of vinyl halides with an intramolecular thiolate moiety: synthesis of 2-alkylidenethietanes
Author/Authors
Lei، نويسنده , , Mao-Yi and Fukamizu، نويسنده , , Koji and Xiao، نويسنده , , Yong-Jun and Liu، نويسنده , , Wei-Min and Twiddy، نويسنده , , Scott and Chiba، نويسنده , , Shunsuke and Ando، نويسنده , , Kaori and Narasaka، نويسنده , , Koichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
4125
To page
4129
Abstract
Various 2-alkylidenethietanes were synthesized by intramolecular nucleophilic substitution reactions at an sp2 carbon of vinyl halides with thiolate moieties. The reaction pathway of the substitution reactions was confirmed as a very rare SNVπ mechanism by theoretical and experimental studies.
Keywords
2-Alkylidenethietane , SNV? mechanism , Nucleophilic vinylic substitution , density functional theory (DFT)
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1859626
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