Author/Authors :
Yadav، نويسنده , , J.S and Subba Reddy، نويسنده , , B.V. and Pandurangam، نويسنده , , T. and Raghavendra Rao، نويسنده , , K.V. and Praneeth، نويسنده , , K. and Narayana Kumar، نويسنده , , G.G.K.S. and Madavi، نويسنده , , C. and Kunwar، نويسنده , , A.C.، نويسنده ,
Abstract :
Various 1,3-dicarbonyl compounds reacted readily with benzylic and propargylic alcohols in the presence of 10 mol % of phosphomolybdic acid supported on silica gel (PMA/SiO2) under mild reaction conditions to produce 2-benzylic- and 2-propargylic-1,3-dicarbonyl compounds in excellent yields and with high selectivity.
Keywords :
3-dicarbonyls , Heteropoly acids , Benzylic/propargylic alcohols , nucleophilic substitution , 1