Title of article :
Ti-catalyzed reactions of 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene with various electrophiles
Author/Authors :
Aouf، نويسنده , , Chahinez and Abed، نويسنده , , Douniazad El and Giorgi، نويسنده , , Michel and Santelli، نويسنده , , Maurice، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
Reductive disilylation (Li + Me3SiCl − THF) of 1,3-cyclohexadiene led to 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene (1). In the presence of TiCl4 in dichloromethane, 1 reacted with some acyl chlorides, anhydrides, and aldehydes to give tricyclo[7.4.0.03,8]trideca-4,12-diene-2-yl derivatives.
Keywords :
Titanium tetrachloride , Electrophilic Substitution , Reductive silylation , 1 , 3-Cyclohexadiene
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
