Title of article :
Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)–CF2SO2Ph reagent
Author/Authors :
Zhang، نويسنده , , Wei and Zhu، نويسنده , , Jieming and Hu، نويسنده , , Jinbo، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
A hypervalent iodine(III)–CF2SO2Ph compound (3) has been successfully prepared with selective nucleophilic reaction using PhSO2CF2SiMe3 reagent, and this previously unkown compound 3 was found to act as a new electrophilic (phenylsulfonyl)difluoromethylation reagent for a variety of S-nucleophiles under very mild reaction conditions.
Keywords :
fluorine , Elctrophilic fluoroalkylation , Hypervalent iodine compound
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
