Author/Authors :
Muranaka، نويسنده , , Atsuya and Yoshida، نويسنده , , Kengo and Akagi، نويسنده , , Yusuke and Naka، نويسنده , , Hiroshi and Uchiyama، نويسنده , , Masanobu and Kondo، نويسنده , , Yoshinori and Kobayashi، نويسنده , , Nagao، نويسنده ,
Abstract :
A solvent-free, solid-phase one-step reaction between tetra-tert-butylated oxotitanium(IV) phthalocyanine and tetraazaporphyrin with 2,3,6,7,10,11-hexahydroxytriphenylene yields novel azaporphyrin cyclic trimers with triangular prismatic orientations. The fluorescence arising from the phthalocyanine and tetraazaporphyrin chromophores is significantly quenched upon trimerization.