• Title of article

    Triptycene as a rigid, 120° orienting, three-pronged, covalent scaffold for porphyrin arrays

  • Author/Authors

    Dahms، نويسنده , , Katja and Senge، نويسنده , , Mathias O.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2008
  • Pages
    3
  • From page
    5397
  • To page
    5399
  • Abstract
    The synthesis of novel porphyrin trimers covalently linked by one central, rigid triptycene unit is described. Reaction of 2,6,14-triiodotriptycene, generated in a three-step synthesis from triptycene, with borylated porphyrins under Suzuki cross-coupling conditions afforded porphyrin trimers. In addition, Sonogashira cross-coupling conditions could be successfully applied for the synthesis of trimeric porphyrin arrays as well.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2008
  • Journal title
    Tetrahedron Letters
  • Record number

    1860803