Author/Authors :
Hirashita، نويسنده , , Tsunehisa and Daikoku، نويسنده , , Yusuke and Osaki، نويسنده , , Hitoshi and Ogura، نويسنده , , Mamiko and Araki، نويسنده , , Shuki، نويسنده ,
Abstract :
Methylenecyclopropanes carrying a hydroxymethyl group at the ring underwent stereoselective allylindation with allylindium sesquiiodide to afford the allylated products, in which the allyl group was delivered at the external sp2 carbon via cyclopropylindium intermediates. The reaction of ethyl 2-cyclopropylideneacetate and triallylindium afforded the 1,4-adduct along with dimeric products.
