Author/Authors :
Hollmann، نويسنده , , Dirk and Bنhn، نويسنده , , Sebastian and Tillack، نويسنده , , Annegret and Parton، نويسنده , , Rudy and Altink، نويسنده , , Rinke and Beller، نويسنده , , Matthias، نويسنده ,
Abstract :
The alkylation of aryl amines using cyclic amines such as pyrrolidine proceeds via borrowing hydrogen methodology in the presence of 1 mol % Shvo catalyst. During the reaction multiple carbon–nitrogen cleavage and formation occurred. This novel reaction sequence leads to N-aryl-pyrrolidines and -piperidines.
Keywords :
Shvo catalyst , amination , Amines , N-Alkylation , Ruthenium