Author/Authors :
Garzelli، نويسنده , , Riccardo and Khlestkin، نويسنده , , Vadim K. and Williams، نويسنده , , Nicholas H. and Chechik، نويسنده , , Victor، نويسنده ,
Abstract :
We have synthesised a series of amphiphilic spin probes containing two nitroxide-functionalised lipophilic branches connected by a disulfide group. The sensitivity of EPR spectroscopy to the interactions between the radical centres in these bisnitroxides makes it possible to monitor the thiol-disulfide exchange reaction in colloidal assemblies.