Title of article
Dialkyltitanium-mediated titanation of conjugated 1,3-butadiynes and its coupling reactions with aldehydes: a facile synthesis of stereodefined enynes and trans-enynols
Author/Authors
Chen، نويسنده , , Jingjin and Liu، نويسنده , , Yuanhong، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
4
From page
6655
To page
6658
Abstract
A highly efficient and convenient method for the selective titanation of 1,3-butadiynes using Ti(OiPr)4/nBuLi reagent has been developed. The method provided a facile synthesis of enynes and trans-enynols in a well-stereodefined manner.
Keywords
Dialkyltitanium complex , Titanium–butadiyne complex , Coupling , Oxatitanacyclopentene , trans-Enynol
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1861588
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