Author/Authors :
Takanami، نويسنده , , Toshikatsu and Matsumoto، نويسنده , , Jun and Kumagai، نويسنده , , Yoko and Sawaizumi، نويسنده , , Aoyo and Suda، نويسنده , , Kohji، نويسنده ,
Abstract :
The first, direct meso-hydroxymethylation of 5,15-substituted porphyrins can effectively be obtained by a simple one-pot procedure involving a sequential SNAr reaction of porphyrins with (2-pyridyldimethylsilyl)methyllithium, followed by hydrolysis and aerobic oxidation at ambient O2 pressure.
