Author/Authors :
Yamasaki، نويسنده , , Ryu and Sotome، نويسنده , , Ikuo and Komagawa، نويسنده , , Shunsuke and Azumaya، نويسنده , , Isao and Masu، نويسنده , , Hyuma and Saito، نويسنده , , Shinichi، نويسنده ,
Abstract :
The Ni-catalyzed [3+2+2] cocyclization between ethyl cyclopropylideneacetate (1) and 1,3-diynes afforded cycloheptadiene derivatives. The three-component reaction of 1, 1,3-diynes, and alkynes proceeded with good yield and high selectivity. Scope of the substrates was studied, and the origin of chemo- and regioselectivity of the reaction is discussed.
