Author/Authors :
Suwabe، نويسنده , , Shin and Okuhara، نويسنده , , Akira and Sugahara، نويسنده , , Takashi and Suzuki، نويسنده , , Keita and Kunimasa، نويسنده , , Katsuhiro and Nakajima، نويسنده , , Toshifumi and Kumafuji، نويسنده , , Yusuke and Osawa، نويسنده , , Yasushi and Yoshimura، نويسنده , , Toshiaki and Morita، نويسنده , , Hiroyuki، نويسنده ,
Abstract :
The irreversible photolytic axial to equatorial change (3ax–4ax→3eq–4eq) and the irreversible thermal equatorial to axial change (3eq–4eq→3ax–4ax) of the S–O configuration were first observed. Meanwhile, the shorter 1,9-bridged derivative (2ax) exhibited the interesting photolytic degradation, affording 1,9-dithiadibenzothiophene (5) by the elimination of SO and ethylene.
Keywords :
Thianthrene , Thermal reaction , Photo reaction , Pyramidal inversion , Intramolecular cyclization
