Title of article :
P′CP′-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines
Author/Authors :
Li، نويسنده , , Jie and Minnaard، نويسنده , , Adriaan J. and Klein Gebbink، نويسنده , , Robertus J.M. and van Koten، نويسنده , , Gerard، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Abstract :
The P′CP′-pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines with allyl(tributyl)stannane is investigated for the preparation of N-homoallylic sulfamides. The desired N,N-dimethylsulfamoyl-protected products are obtained in moderate to high yields in DMF under very mild conditions and a high yielding and convenient deprotection of the N,N-dimethylsulfamoyl group is also demonstrated.
Keywords :
P?CP?-Pincer catalysis , Homoallylation , N-Dimethylsulfamoyl protecting group , Aldimines , N , PALLADIUM
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
