Author/Authors :
Volkova، نويسنده , , Yuliya A. and Ivanova، نويسنده , , Olga A. and Budynina، نويسنده , , Ekaterina M. and Revunov، نويسنده , , Eugene V. and Averina، نويسنده , , Elena B.، نويسنده ,
Abstract :
A novel approach to nitro-substituted cyclopropanes and spiropentanes via oxidation of the corresponding amines with dimethyldioxirane is reported. The method is used successfully for the preparation of a series of nitrocyclopropanes as well as for the first synthesis of 1,4-dinitrospiro[2.2]pentane.
Keywords :
Cyclopropanes , Oxidation , Nitro-compounds , Dimethyldioxirane