Author/Authors :
Villorbina، نويسنده , , Gemma and Tomàs، نويسنده , , Albert and Escribà، نويسنده , , Marc and Oromي-Farrْs، نويسنده , , Mireia and Eras، نويسنده , , Jordi and Balcells، نويسنده , , Mercè and Canela، نويسنده , , Ramon، نويسنده ,
Abstract :
We describe here the first example in which glycerol has been transformed into chlorohydrin esters using an ionic liquid and hydrated aluminium chloride. The method avoids using Crown-18 ether, which was needed to obtain a similar yield when KCl was used. Alkyl and aryl acids can be used, although yields are very dependent on the carboxylic acid used.
Keywords :
Glycerol , Chlorohydrin esters , Ionic liquid , Hydrated aluminium chloride , Substitution , MP