Title of article :
Diels–Alder reactivity of anti-tricyclo[4.2.1.12,5]deca-3,7-diene derivatives
Author/Authors :
Etzkorn، نويسنده , , Markus and Amado-Sierra، نويسنده , , Maria del Rosario I. and Smeltz، نويسنده , , Steven D. and Gerken، نويسنده , , Michael، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Abstract :
The limited thermal stability of the polycyclic dione 1 can be circumvented by reacting its derivatives, hydroxyketone 3 and diol 4 with tetrachlorothiophene dioxide (6d) to yield the mono-Diels–Alder adduct 8 and rearranged polycyclic ether 11, respectively. The structures of both new products were confirmed by X-ray structure determination.
Keywords :
transannular reaction , polycyclic compounds , Diels–Alder cycloaddition , benzannulation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
