Author/Authors :
Lin، نويسنده , , Zi-Ping and Lin، نويسنده , , Hui-Chang and Wu، نويسنده , , Hsu-Hsuan and Chou، نويسنده , , Hsiu-Wen and Lin، نويسنده , , Shao-Kai and Sung، نويسنده , , Kuan-Chin and Wong، نويسنده , , Fung Fuh، نويسنده ,
Abstract :
β-Enamino ketones were successfully synthesized in good to excellent yields by reaction of hex-1-en-3-uloses with amines. After hydrogenation on palladium catalyst, β-enamino ketones effectively underwent hydrodeamination and were converted to the corresponding 1,2-dideoxy-d-threo-3-hexulose derivatives in 89–95% yields.
Keywords :
Hydrodeamination , ?-Enamino ketones , ?-mannosidase , Hex-1-en-3-ulose
