Title of article
Iodoetherification of unactivated alkenes catalyzed by diphosphine palladium(II) complexes
Author/Authors
Derek M. Doroski، نويسنده , , Todd A. and Cox، نويسنده , , Matthew R. and Morgan، نويسنده , , Jeremy B.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
5162
To page
5164
Abstract
A palladium-catalyzed intramolecular iodoetherification of alkenes is reported. The reaction is efficient and highly diastereoselective for disubstituted alkenes. The tether length between the alcohol and alkene can be varied to produce tetrahydrofuran and tetrahydropyran rings. Diphosphine palladium(II) salts are highly active catalysts enabling future studies on the development of an enantioselective process.
Keywords
Palladium catalysis , tetrahydropyrans , iodination , tetrahydrofurans
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865686
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