Title of article
Diallylation of 2,2-dialkylbenzodioxoles from TiCl4-mediated allylsilane reaction
Author/Authors
Galy، نويسنده , , Nicolas and Moraleda، نويسنده , , Delphine and Santelli، نويسنده , , Maurice، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
5238
To page
5240
Abstract
Reaction of aliphatic ketones with catechol afforded 2,2-dialkylbenzodioxoles. Treatment of these benzodioxoles with allyltrimethylsilane in the presence of titanium tetrachloride led to 4,4-dialkylhepta-1,6-dienes resulting from a diallylation process. Ring-closing metathesis gave rise to 4,4-dialkylcyclopentenes.
Keywords
Allylsilane , Benzodioxoles , Diallylation , Titanium tetrachloride , Nitromethane , metathesis
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1865743
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