Author/Authors :
Sakurai، نويسنده , , Fumie and Kondo، نويسنده , , Kazuhiro and Aoyama، نويسنده , , Toyohiko، نويسنده ,
Abstract :
The Ni-catalyzed asymmetric arylation of benzaldehydes bearing an ortho-masked H group with potassium aryltriolborates has been developed. The keys to success were (i) steric tuning of benzaldehyde derivatives with an ortho-Me2PhSi group, and (ii) the use of potassium aryltriolborates as aryl sources.
