Title of article
Photodecarboxylative benzylations of phthalimides
Author/Authors
Hatoum، نويسنده , , Fadi and Gallagher، نويسنده , , Sonia and Baragwanath، نويسنده , , Louise and Lex، نويسنده , , Johann and Oelgemِller، نويسنده , , Michael، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
6335
To page
6338
Abstract
Photoadditions of phenylacetates to phthalimides give the corresponding benzylated hydroxyphthalimidines in moderate to high yields of 29–90%. With 2-phenylpropanoate, photoaddition affords a diastereoisomeric mixture in a de of 24% in favour of the like-diastereoisomer. l-3-Phenyl lactate and 2-oxo-3-phenylpropanoate both furnish the benzylated product through subsequent loss of formaldehyde and decarbonylation, respectively.
Keywords
photodecarboxylation , benzylation , Phthalimides , photochemistry , photoinduced electron transfer
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866524
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