Title of article
A useful synthetic equivalent of an acetone enolate
Author/Authors
Maslak، نويسنده , , Veselin and Tokic-Vujosevic، نويسنده , , Zorana and Ferjancic، نويسنده , , Zorana and Saicic، نويسنده , , Radomir N.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
6709
To page
6711
Abstract
2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers.
Keywords
allylation , Aldehydes , Zinc , aldol reaction , Indium , water
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1866802
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